MSDS
| Product Name | GLUTARALDEHYDE |
| Part Number | RXSOL-19-1196-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
| Phone | +91 22 65113333 / 5555 / 9999 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| 123@rxmarine.com | |
| Website | www.rxmarine.com |
| Name of Substance | Cas Number | EC Number | Wight % |
| Glutaraldehyde | 111-30-8 | 203-856-5 | 50% |
| Non Hazardous Ingirdent | 50 % |
| Signal Word | Danger |
| Hazard Statements |
H302 + H332 Harmful if swallowed or if inhaled. H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract |
| Precautionary statements - prevention |
P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. |
| Precautionary statements - response |
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician. |
| Eye Contact | Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. |
| Skin Contact | In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. |
| Inhalation: | Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
| Ingestion: | Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. |
| Notes to Physician | Treat symptomatically |
| Flammability | Non-flammable. |
| Flash Point | Not applicable. |
| Suitable extinguishing media | No information available |
|
Hazardous combustion products |
When heated to decomposition, it emits acrid smoke and fumes. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical | Not considered to be a significant fire risk. |
| Small Spillage | Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts |
| Handling | Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids. |
| Storage | Light Sensitive. Refrigerate. Store in light-resistant containers. Keep containers tightly closed. Keep containers in a cool, wellventilated area.Packing : Only packagings which are approved (e.g. acc. to ADR) may be used. |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Engineering Control | Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. |
| Personal Protection |
Eye/face Protection : Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection : Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection : Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Exposure Limit | Glutaraldehyde TWA: 0.2 (ppm) [Australia] TWA: 0.82 (mg/m3) [Australia] TWA: 0.25 CEIL: 0.2 (ppm) from NIOSH CEIL: 0.2 (ppm) from OSHA (PEL) [United States] TWA: 0.05 STEL: 0.05 (ppm) [United Kingdom (UK)] Consult local authorities for acceptable exposure limits. |
Gloves Suit
| Form | Liquid |
| Colour | Clear |
| Odour | Pungent |
| Odor Threshold | No Information Available |
| pH | 3.5 - 4.5 |
| Freezing Point | -13 °C |
| Boiling Point | 101°C |
| Flash Point | Not Applicable |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No Data Available |
| Explosive limits | No Data Available |
| Vapour pressure | 21 hPa at 20 °C |
| Vapour Density | 0.8 |
| Relative density Information | 1.10 at 25 °C |
| Partition coefficient | No data available |
| Explosive properties | None |
| Solubility | Soluble in water |
| Ignition temperature | 275 °C |
| Recativity | Forms explosive mixtures with air on intense heating. |
| Stability | Product is stable. |
| Possibility of hazardous reactions |
Violent reactions possible with:Amines, Strong oxidizing agents Violent polymerisation may be caused by: Strong bases, Strong acids |
| Conditions to avoid | Strong Heating |
| Incompatible materials | Aluminium, various metals, Mild steel |
| Hazardous Polymerization | Hazardous polymerization does not occur. |
| Rout Of Entry | Absorbed through skin. Eye contact. Inhalation. Ingestion. |
| Toxicity to Animal | WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 100 mg/kg [Mouse]. Acute dermal toxicity (LD50): >2500 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 480 mg/m 4 hours [Rat]. 3 |
| Toxic Effects on Humans |
CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for human or animal.) by ACGIH [Glutaraldehyde]. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Glutaraldehyde]. Mutagenic for bacteria and/or yeast. [Glutaraldehyde]. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [SUSPECTED] [Glutaraldehyde]. Contains material which may cause damage to the following organs: blood, the reproductive system, liver, mucous membranes, spleen, central nervous system (CNS), Urinary system. |
| Special Remarks on other Toxic Effects on Humans: |
Potential Health Effects: Eye: Causes severe eye irritation. May cause eye injury or chemical conjunctivitis. Skin: Causes moderate to severe skin irritation. It may be absorbed through the skin, although poorly. May cause allergic contact dermatitis with itching and skin rash. May cause staining of the skin and nails to a brown or golden brown color. Ingestion: Harmful if swallowed. May cause severe irritation of the digestive tract with burning sensation in the chest, abdominal pain, cramping, vomiting, diarrhea (perhaps bloody diarrhea), vascular collapse, and coma. May also affect liver (increased liver enzymes, liver damage), spleen, blood (normocytic anemia), metabolism (weight loss), behavior (somnolence, excitement, dizziness, lethargy, ataxia, seizures), metabolism (weight loss), urinary system ( abnormal reneal function, anuria) Inhalation: Harmful if inhaled. Can cause respiratory tract irritation and sudden headaches. |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products of Biodegradation: | No Information available |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | Substance(s) in the mixture do(es) not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII, or a PBT/vPvB assessment was not conducted.. |
| Other adverse effects | Discharge into the environment must be avoided. |
| Waste treatment Method | Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself |
DOT
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
TDG
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
IATA
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
IMDG/IMO
| UN Number | UN1307 |
| Proper shipping name |
CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE SOLUTION) |
| Hazard Class | 8 |
| Packing group | II |
| Fedral and State Regulation | Pennsylvania RTK: Glutaraldehyde Florida: Glutaraldehyde Massachusetts RTK: Glutaraldehyde New Jersey: Glutaraldehyde California Director's list of Hazardous Substances: Glutaraldehyde TSCA 8(b) inventory: Glutaraldehyde; Water TSCA 8(a) PAIR: Glutaraldehyde TSCA 8(d) H and S data reporting: Glutaraldehyde: 9/30/91 to 9/30/01 |
| Other Regulation | OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. |
| WHMIS (Canada) | CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC). CLASS E: Corrosive liquid. |
| DSCL (EEC) | R36- Irritating to eyes. S2- Keep out of the reach of children. S24/25- Avoid contact with skin and eyes. S46- If swallowed, seek medical advice immediately and show this container or label. |
| HMIS | |
| Health Hazard | : 2 |
| Fire Hazard | : 0 |
| Reactivity | : 0 |
| Personal Protection | : H |
| Fire : | |
| Health Hazard | : 2 |
| Fire Hazard | : 0 |
| Reactivity | : 0 |
| Specific Hazard | : H |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. |
| Product Name | PHTHALIC ANHYDRIDE |
| Part Number | RXSOL-19-1612-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
| Phone | +91 22 65113333 / 5555 / 9999 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| 123@rxmarine.com | |
| Website | www.rxmarine.com |
| Name of Substance | Cas Number | EC Number | Wight % |
| Phthalic Anhydride | 85-44-9 | 201-607-5 | 99.8-100% |
| Maleic Anhydride | 108-31-6 | 203-571-6 | 0.01 - 0.05% |
| SignalWord | Danger |
| Hazard Statements |
H302 Harmful if swallowed. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. |
| Precautionary statements - prevention |
P280 Wear protective gloves. P280 Wear eye protection. |
| Precautionary statements - response |
P302 + P352 IF ON SKIN: Wash with plenty of soap and water. |
| Eye Contact |
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention. |
| Skin Contact | In case of contact, immediately flushes skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. |
| Inhalation: | Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
| Ingestion: | Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. |
| Notes to Physician | Treat symptomatically |
| Flammability | May be combustible at high temperature. |
| Auto Ignition Temperature | 570°C |
| Flash Point | Close Cup: 151.67°C.Open Cup: 165°C |
| Suitable extinguishing media | Water, Carbon dioxide (CO2), Foam, Dry powder |
| Hazardous combustion products | Forms explosive mixtures with air on intense heating. Risk of dust explosion. Development of hazardous combustion gases or vapours possible in the event of fire. |
| Fire Fighting Media and Instructions | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Further Information | Cool closed containers exposed to fire with water spray. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
| Spillage | Use appropriate tools to put the spilled solid in a convenient waste disposal container. Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid substance contact. Avoid inhalation of dusts. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. |
| Methods and materials for containment and cleaning | Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Handling |
Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents. |
| Storage | Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons. |
| Advice general occupational | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended nexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Personal Protection |
Eye/face Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection: Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection : Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced. |
| Exposure Limit | TWA: 6.1 (mg/m3) from ACGIH (TLV) [United States] TWA: 6 from ACGIH (TLV) [United States]Consult local authorities for acceptable exposure limits. |
Gloves Suit
| Form | Solid |
| Colour | White |
| Odour | Characteristic |
| Odor Threshold | Not Applicable |
| pH | 2 at 6 g/l 20 °C |
| Melting Point | 131 °C (decomposition) |
| Boiling Point | 285°C |
| Flash Point | 152 °C Method: DIN 51758 |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No Data Available |
| Lower Explosion limits | 1.7 %(V) |
| Upper explosion limit | 10.5 %(V) |
| Vapour pressure | < 0.01 hPa at 20 °C |
| Vapour Density | 6.6 |
| Specific Gravity | 1.527 g/cm³ at 20 °C |
| Partition coefficient | n-octanol/water log Pow: 2.07 (25 °C) (calculated) |
| Explosive properties | Not classified as explosive. |
| Solubility | Soluble in water 6 g/l at 20 °C |
| Ignition temperature | 580 °C Method: DIN 51794 |
| Viscosity, dynamic | No information available |
| Reactivity | Risk of dust explosion. Forms explosive mixtures with air on intense heating. |
| Stability | The product is chemically stable under standard ambient conditions (room temperature). |
| Possibility of hazardous reaction |
Violent reactions possible with: Strong acids, Organic acids, strong reducing agents, Water, alkali hydroxides, Nitric acid, Alcohols, glycerol, metallic oxides, nitrites, Oxidizing agents, Air metals, (in the presence of atmospheric oxygen and/or moisture) |
| Conditions to avoid | Strong Heating |
| Incompatible materials | Rubber Various Plastic |
| Hazardous Polymerization | Hazardous polymerization does not occur. |
| Rout Of Entry | Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. |
| Toxicity to Animal | WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1500 mg/kg [Mouse]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50): >210 mg/m 1 hours [Rat]. |
| Toxic Effects on Human | Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive). |
| Special Remarks on other Toxi Effects on Humans: |
Acute Potential Health Effects: Corrosive! If the solid materials is permitted to remain in contact with moist tissues, superficial burns may result. Skin: May cause severe skin irritation witn possible skin burns. If the skin is moist the irritant effects will be greater due to hydrolysis of phthalic acid. Eyes: May cause severe eye irritation with possible eye burns. May cause chemical conjunctivitis and corneal damage. Inhalation: Causes severe respiratory tract irritation with possible chemical burns to the respiratory tract. May cause asthmatic attacks due to allergic sensitization of respiratory tract. May also affect respiration, and liver. Symptoms may include Rhinorrhea, blaody nasal disharge, hoarseness of voice, cough, bronchospasm Ingestion: Causes severe digestive tract irritation iwth possible burns. May cause severe and permanent damage to the digestive tract. Mah cause perforation of the digestive tract. May affect behavior. Chronic Potential Health Effects: Skin: Prolonged or repeated skin contact may cause allergic skin reaction. |
| Eco Toxicity | Not Available |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | 99 %; 14 d OECD Test Guideline 301E Readily biodegradable. |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | PBT/vPvB assessment not available as chemical safety assessment not required/not conducted. |
| Other adverse effects | Additional ecological information Biological effects: Harmful effect due to pH shift. Discharge into the environment must be avoided. |
| Waste treatment Method | Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself |
DOT
| UN Number | UN 2214 |
| Proper shipping name | PHTHALIC ANHYDRIDE |
| Hazard Class | 8 |
| Packing group | III |
| Special Provisions for Transport | Not Classified as Hazardous for Transport |
TDG
| UN Number | UN 2214 |
| Proper shipping name | PHTHALIC ANHYDRIDE |
| Hazard Class | 8 |
| Packing group | III |
| Special Provisions for Transport | Not Classified as Hazardous for Transport |
IATA
| UN Number | UN 2214 |
| Proper shipping name | PHTHALIC ANHYDRIDE |
| Hazard Class | 8 |
| Packing group | III |
| Special Provisions for Transport | Not available. |
IMDG/IMO
| UN Number | UN 2214 |
| Proper shipping name | PHTHALIC ANHYDRIDE |
| Hazard Class | 8 |
| Packing group | III |
| Special Provisions for Transport | Not Classified as Hazardous for Transport |
| Fedral and State Regulation | Connecticut hazardous material survey.: Phthalic anhydride Illinois toxic substances disclosure to employee act: Phthalic anhydride Illinois chemical safety act: Phthalic anhydride New York release reporting list: Phthalic anhydride Rhode Island RTK hazardous substances: Phthalic anhydride Pennsylvania RTK: Phthalic anhydride Minnesota: Phthalic anhydride Michigan critical material: Phthalic anhydride Massachusetts RTK: Phthalic anhydride |
| Other Regulation | OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. |
| WHMIS (Canada) | CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid. |
| DSCL (EEC) | R22- Harmful if swallowed. R26- Very toxic by inhalation. R38- Irritating to skin. R41- Risk of serious damage to eyes. S1/2- Keep locked up and out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of [***] S36/37- Wear suitable protective clothing and gloves. S39- Wear eye/face protection. S45- In case of accident or if you feel unwell, |
| HMIS | |
| Health Hazard | : 3 |
| Fire Hazard | : 1 |
| Reactivity | : 1 |
| Personal Protection | : E |
| Fire : | |
| Health Hazard | : 3 |
| Fire Hazard | : 1 |
| Reactivity | : 0 |
| Specific Hazard | : |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. |
| Product Name | Sodium Fluoride |
| Part Number | RXSOL-19-8203-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
| Phone | +91 22 65113333 / 5555 / 9999 |
| Fax | +91 22 2781 1318 :::AOH :0091 9821214367 |
| 123@rxmarine.com | |
| Website | www.rxmarine.com |
| Name of Substance | Cas Number | EC Number | Wight % |
| Sodium Fluoride | 7681-49-4 | 231-667-8 | 100% |
| Signal Word | Danger |
| Hazard Statements |
H301 Toxic if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. EUH032 Contact with acids liberates very toxic gas. |
| Precautionary statements - prevention | P280 Wear protective gloves. |
| Precautionary statements response |
P302 + P352 IF ON SKIN: Wash with plenty of soap and water. |
| Eye Contact |
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention. |
| Skin Contact | In case of contact, immediately flushes skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. |
| Inhalation: | Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
| Ingestion: | Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. |
| Notes to Physician | Treat symptomatically |
| Flammability | Not Flammable |
| Flash Point | Not Applicable |
| Suitable extinguishing media | Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. |
| Hazardous combustion products | Not available |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical | Not combustible. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: Hydrogen fluoride |
| Special protective equipment for firefighters | Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
| Spillage |
Use appropriate tools to put the spilled solid in a convenient waste disposal container.Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up the affected area. Avoid generation of dust |
| Handling |
Do not ingest. Do not breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals, acids, alkalis. |
| Storage | Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.Protect from moisture. Store away from foodstuffs |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Personal Protection |
Eye/face Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin and body protection: Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection : Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Exposure Limit | TWA: 2.5 (mg/m3) from NIOSH Consult local authorities for acceptable exposure limits |
Gloves Suit
| Form | Crystal / Solid |
| Colour | White |
| Odour | Odourless |
| Odor Threshold | Not Applicable |
| pH | 10.2 at 40 g/l 20 °C |
| Melting Point | 996 °C (decomposition) |
| Boiling Point | 1,695 °C at 1,013 hPa |
| Flash Point | Not Applicable |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No Data Available |
| Explosive limits | No Data Available |
| Vapour pressure | 1 hPa at 1,077 °C |
| Vapour Density | No information available. |
| Specific Gravity | 2.8 g/cm3 at 20 °C |
| Partition coefficient | No data available |
| Explosive properties | None |
| Solubility | Soluble in water 50 g/l at 20 °C |
| Ignition temperature | No information available. |
| Oxidizing properties | None |
| Reactivity | Reacts with acids.. |
| Stability | The product is chemically stable under standard ambient conditions. |
| Possibility of hazardous reactions | Generates dangerous gases or fumes in contact with: acids Possible formation of : Hydrogen Fluoride. |
| Conditions to avoid | Strong Heating |
| Incompatible materials | Reactive with oxidizing agents, metals, acids, alkalis. |
| Hazardous Polymerization | Hazardous polymerization does not occur. |
| Rout Of Entry | Inhalation. Ingestion. |
| Toxicity to Animal | Acute oral toxicity (LD50): 52 mg/kg [Rat]. |
| Toxic Effects on Human | May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
| Special Remarks on other Toxi Effects on Humans: |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
| Further Information |
After absorption: We have no description of any toxic symptoms. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. Systemic effects: Cardiac irregularities, respiratory arrest, Nausea, Unconsciousness, death The following applies to soluble inorganic fluorides in general: may cause irritations to burns in contact with eyes, skin, mucous membranes. Systemic effect: drop in blood calcium level, agitation, spasms, cardiovascular disorders, CNS disorders. Handle in accordance with good industrial hygiene and safety practice |
| Eco Toxicity | Toxicity to fish : LC50 Gambusia affinis (Mosquito fish): 925 mg/l; 96 h (IUCLID). Toxicity to daphnia and other aquatic invertebrates EC50 Daphnia magna (Water flea): 338 mg/l; 48 h (IUCLID) |
| COD and BOD 5 | Not Available |
| Products Biodegradation: | Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | PBT/vPvB assessment not available as chemical safety assessment not required/not conducted |
| Other adverse effects | Hazard for drinking water supplies. Discharge into the environment must be avoided. |
| Waste treatment Method | Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. |
DOT
| UN Number | UN 1690 |
| Proper shipping name |
SODIUM FLUORIDE, SOLID |
| Hazard Class | 6.1 |
| Packing group | III |
TDG
| UN Number | UN 1690 |
| Proper shipping name |
SODIUM FLUORIDE, SOLID |
| Hazard Class | 6.1 |
| Packing group | III |
IATA
| UN Number | UN 1690 |
| Proper shipping name |
SODIUM FLUORIDE, SOLID |
| Hazard Class | 6.1 |
| Packing group | III |
IMDG/IMO
| UN Number | UN 1690 |
| Proper shipping name |
SODIUM FLUORIDE, SOLID |
| Hazard Class | 6.1 |
| Packing group | III |
| Fedral and State Regulation | California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. Connecticut hazardous material survey.: Sodium fluoride Illinois chemical safety act: Sodium fluoride New York release reporting list: Sodium fluoride Rhode Island RTK hazardous substances: Sodium fluoride Pennsylvania RTK: Sodium fluoride Massachusetts RTK: Sodium fluoride Massachusetts spill list: Sodium fluoride New Jersey: Sodium fluoride New Jersey spill list: Sodium fluoride Louisiana spill reporting: Sodium fluoride. |
| Other Regulation | OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. |
| WHMIS (Canada) | CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC). |
| DSCL (EEC) | R25- Toxic if swallowed. R32- Contact with acids liberates very toxic gas. R36/38- Irritating to eyes and skin. S22- Do not breathe dust. S36- Wear suitable protective clothing. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). |
| HMIS | |
| Health Hazard | : 2 |
| Fire Hazard | : 0 |
| Reactivity | : 0 |
| Personal Protection | : E |
| Fire : | |
| Health Hazard | : 3 |
| Fire Hazard | : 0 |
| Reactivity | : 0 |
| Specific Hazard | : |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. |
