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Product Name GLUTARALDEHYDE
Part Number RXSOL-19-1196-025

Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.

VASHI ,NEW BOMBAY 400703 INDIA

 

 

 

Phone +91 22 65113333 / 5555 / 9999
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email 123@rxmarine.com
Website www.rxmarine.com

 

 

 

Name     of        Substance                          Cas Number EC Number Wight %
Glutaraldehyde 111-30-8 203-856-5  50%
Non Hazardous Ingirdent      50 %

 

 

 

 

Signal Word                        Danger
Hazard Statements H302 + H332 Harmful if swallowed or if inhaled.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H410 Very toxic to aquatic life with long lasting effects.
EUH071 Corrosive to the respiratory tract
Precautionary statements - prevention P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
Precautionary statements - response P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.

  

 

 

 

Eye Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
Skin Contact In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur.
Ingestion: Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
Notes to Physician Treat symptomatically

 

 

Flammability                                                  Non-flammable.
Flash Point Not applicable.
Suitable extinguishing media No information available
Hazardous combustion
products
When heated to decomposition, it emits acrid smoke and fumes.
Protective Equipment Use personal protective equipment.
Specific Hazards Arising from the Chemical Not considered to be a significant fire risk.  

 

 

Small Spillage Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements
Personal Protection Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution Do not let product enter drains.
Methods and materials for
containment and cleaning
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts

 

 

 

 

Handling Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, acids.
Storage Light Sensitive. Refrigerate. Store in light-resistant containers. Keep containers tightly closed. Keep containers in a cool, wellventilated area.Packing : Only packagings which are approved (e.g. acc. to ADR) may be used.
Advice on general occupational hygiene Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.

 

 

Engineering Control Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection Eye/face Protection :  Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection : Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection :  Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator  exposure limits are exceeded or if irritation or other symptoms are experienced.
Other Protection Measure Handle in accordance with good industrial hygiene and safety practice.
Exposure Limit Glutaraldehyde TWA: 0.2 (ppm) [Australia] TWA: 0.82 (mg/m3) [Australia] TWA: 0.25 CEIL: 0.2 (ppm) from NIOSH CEIL: 0.2 (ppm) from OSHA (PEL) [United States] TWA: 0.05 STEL: 0.05 (ppm) [United Kingdom (UK)] Consult local authorities for acceptable exposure limits.

       gloves                suit                

        Gloves                       Suit                          

 

 

Form         Liquid
Colour Clear
Odour Pungent
Odor Threshold No Information Available
pH 3.5 - 4.5 
Freezing Point -13 °C
Boiling Point 101°C
Flash Point Not Applicable
Evaporation Rate Not Applicable
Flammability (solid, gas) No Data Available
Explosive limits No Data Available
Vapour pressure 21 hPa at 20 °C
Vapour Density 0.8
Relative density Information 1.10  at 25 °C
Partition coefficient No data available
Explosive properties None
Solubility Soluble in water
Ignition temperature 275 °C

 

 

Recativity                        Forms explosive mixtures with air on intense heating.
Stability Product is stable.
Possibility of hazardous reactions Violent reactions possible with:Amines, Strong oxidizing agents
Violent polymerisation may be caused by: Strong bases, Strong acids
Conditions to avoid Strong Heating
Incompatible materials Aluminium, various metals, Mild steel
Hazardous Polymerization Hazardous polymerization does not occur.

 

 

 

Rout Of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion.
Toxicity to Animal WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 100 mg/kg [Mouse]. Acute dermal toxicity (LD50): >2500 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 480 mg/m 4 hours [Rat]. 3
Toxic Effects on Humans CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for human or animal.) by ACGIH [Glutaraldehyde]. MUTAGENIC
EFFECTS: Mutagenic for mammalian somatic cells. [Glutaraldehyde]. Mutagenic for bacteria and/or yeast. [Glutaraldehyde].
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male [SUSPECTED]
[Glutaraldehyde]. Contains material which may cause damage to the following organs: blood, the reproductive system, liver,
mucous membranes, spleen, central nervous system (CNS), Urinary system.
Special Remarks on other Toxic Effects on Humans:

Potential Health Effects: Eye: Causes severe eye irritation. May cause eye injury or chemical conjunctivitis. Skin: Causes moderate to severe skin irritation. It may be absorbed through the skin, although poorly. May cause allergic contact dermatitis with itching and skin rash. May cause staining of the skin and nails to a brown or golden brown color. Ingestion: Harmful if swallowed. May cause severe irritation of the digestive tract with burning sensation in the chest, abdominal pain, cramping, vomiting, diarrhea (perhaps bloody diarrhea), vascular collapse, and coma. May also affect liver (increased liver enzymes, liver damage), spleen, blood (normocytic anemia), metabolism (weight loss), behavior (somnolence, excitement, dizziness, lethargy, ataxia, seizures), metabolism (weight loss), urinary system ( abnormal reneal function, anuria) Inhalation: Harmful if inhaled. Can cause respiratory tract irritation and sudden headaches.

 

 

Eco Toxicity Not Available
COD and BOD 5 Not Available
Products of Biodegradation: No Information available
Mobility in soil No Information available
Results of PBT and vPvB assessment Substance(s) in the mixture do(es) not meet the criteria for PBT or vPvB according to Regulation (EC) No 1907/2006, Annex XIII, or a PBT/vPvB assessment was not conducted..
Other adverse effects Discharge into the environment must be avoided.

 

 

 

Waste treatment Method Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself

DOT

 

 

UN        Number                                          UN1307
Proper shipping name CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class 8
Packing group II

TDG

 

 

UN        Number                                          UN1307
Proper shipping name CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class 8
Packing group II

IATA

 

 

UN        Number                                          UN1307
Proper shipping name CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class 8
Packing group II

IMDG/IMO

 

 

UN        Number                                          UN1307
Proper shipping name CORROSIVE LIQUID, N.O.S. (GLUTARDIALDEHYDE
SOLUTION)
Hazard Class 8
Packing group II

 

 

Fedral and State Regulation  Pennsylvania RTK: Glutaraldehyde Florida: Glutaraldehyde Massachusetts RTK: Glutaraldehyde New Jersey: Glutaraldehyde California Director's list of Hazardous Substances: Glutaraldehyde TSCA 8(b) inventory: Glutaraldehyde; Water TSCA 8(a) PAIR: Glutaraldehyde TSCA 8(d) H and S data reporting: Glutaraldehyde: 9/30/91 to 9/30/01
Other Regulation OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada) CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC). CLASS E: Corrosive liquid.
DSCL (EEC) R36- Irritating to eyes. S2- Keep out of the reach of children. S24/25- Avoid contact with skin and eyes. S46- If swallowed, seek medical advice immediately and show this container or label.

 

 

 

 

 

HMIS                               
Health Hazard : 2
Fire Hazard : 0
Reactivity : 0
Personal Protection : H

 

 

 

Fire :                              
Health Hazard : 2
Fire Hazard : 0
Reactivity : 0
Specific Hazard : H

 

 

 

Other Information  

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  we assume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.



 

 

Product Name PHTHALIC ANHYDRIDE
Part Number RXSOL-19-1612-025

Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.

VASHI ,NEW BOMBAY 400703 INDIA

 

 

 

Phone +91 22 65113333 / 5555 / 9999
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email 123@rxmarine.com
Website www.rxmarine.com

 

 

 

Name     of        Substance                          Cas Number EC Number Wight %
Phthalic Anhydride 85-44-9 201-607-5  99.8-100%
Maleic Anhydride 108-31-6 203-571-6  0.01 - 0.05%

 

 

 

 

SignalWord                        Danger
Hazard Statements H302 Harmful if swallowed.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
Precautionary statements - prevention P280 Wear protective gloves.
P280 Wear eye protection.
Precautionary statements - response

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

  

 

 

 

Eye Contact

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Skin Contact In case of contact, immediately flushes skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur.
Ingestion: Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
Notes to Physician Treat symptomatically

 

 

Flammability                                                 May be combustible at high temperature.
Auto   Ignition Temperature 570°C
Flash Point Close Cup: 151.67°C.Open Cup: 165°C
Suitable extinguishing media Water, Carbon dioxide (CO2), Foam, Dry powder
Hazardous combustion products Forms explosive mixtures with air on intense heating. Risk of dust explosion. Development of hazardous combustion gases or vapours possible in the event of fire.
Fire Fighting Media and Instructions Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further Information Cool closed containers exposed to fire with water spray. Prevent fire extinguishing water from contaminating surface water or the ground water system.

 

 

Spillage                    Use appropriate tools to put the spilled solid in a convenient waste disposal container. Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Personal Protection Advice for non-emergency personnel: Avoid substance contact. Avoid inhalation of dusts. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution Do not let product enter drains.
Methods and materials for containment and cleaning Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.

 

 

 

Handling

Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents.

Storage Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.
Advice general occupational Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.

 

 

 

Engineering Control Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended nexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection Eye/face Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection: Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection :  Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced.
Exposure Limit TWA: 6.1 (mg/m3) from ACGIH (TLV) [United States] TWA: 6 from ACGIH (TLV) [United States]Consult local authorities for acceptable exposure limits.

       gloves                suit                

        Gloves                       Suit                          

 

 

Form         Solid
Colour White
Odour Characteristic
Odor Threshold Not Applicable
pH 2 at 6 g/l 20 °C
Melting Point 131 °C (decomposition)
Boiling Point 285°C
Flash Point 152 °C Method: DIN 51758
Evaporation Rate Not Applicable
Flammability (solid, gas) No Data Available
Lower Explosion limits 1.7 %(V)
Upper explosion limit 10.5 %(V)
Vapour pressure < 0.01 hPa at 20 °C
Vapour Density 6.6
Specific Gravity 1.527 g/cm³ at 20 °C
Partition coefficient  n-octanol/water log Pow: 2.07 (25 °C) (calculated)
Explosive properties Not classified as explosive.
Solubility Soluble in water 6 g/l at 20 °C
Ignition temperature 580 °C Method: DIN 51794
 Viscosity, dynamic No information available


 

 

 

Reactivity                        Risk of dust explosion. Forms explosive mixtures with air on intense heating.
Stability The product is chemically stable under standard ambient conditions (room temperature).
Possibility of hazardous reaction Violent reactions possible with:
Strong acids, Organic acids, strong reducing agents, Water, alkali hydroxides, Nitric acid, Alcohols, glycerol, metallic oxides, nitrites, Oxidizing agents, Air metals, (in the presence of atmospheric oxygen and/or moisture)
Conditions to avoid Strong Heating
Incompatible materials Rubber Various Plastic
Hazardous Polymerization Hazardous polymerization does not occur.

 

 

 

Rout Of Entry Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.
Toxicity to Animal WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 1500 mg/kg [Mouse]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50): >210 mg/m 1 hours [Rat].
Toxic Effects on Human Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive, permeator), of eye contact (corrosive).
Special Remarks on other Toxi  Effects on Humans:                      

Acute Potential Health Effects: Corrosive! If the solid materials is permitted to remain in contact with moist tissues, superficial burns may result. Skin: May cause severe skin irritation witn possible skin burns. If the skin is moist the irritant effects will be greater due to hydrolysis of phthalic acid. Eyes: May cause severe eye irritation with possible eye burns. May cause chemical conjunctivitis and corneal damage. Inhalation: Causes severe respiratory tract irritation with possible chemical burns to the respiratory tract. May cause asthmatic attacks due to allergic sensitization of respiratory tract. May also affect respiration, and liver. Symptoms may include Rhinorrhea, blaody nasal disharge, hoarseness of voice, cough, bronchospasm Ingestion: Causes severe digestive tract irritation iwth possible burns. May cause severe and permanent damage to the digestive tract. Mah cause perforation of the digestive tract. May affect behavior. Chronic Potential Health Effects: Skin: Prolonged or repeated skin contact may cause allergic skin reaction.

 

 

 

Eco Toxicity Not Available
COD and BOD 5 Not Available
Products Biodegradation: 99 %; 14 d OECD Test Guideline 301E Readily biodegradable.
Mobility in soil No Information available
Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted.
Other adverse effects Additional ecological information Biological effects: Harmful effect due to pH shift. Discharge into the environment must be avoided.

 

 

 

Waste treatment Method Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself

DOT

 

 

UN        Number                                          UN 2214
Proper shipping name PHTHALIC ANHYDRIDE
Hazard Class 8
Packing group III
Special Provisions for Transport Not Classified as Hazardous for Transport

TDG

 

 

UN        Number                                          UN 2214
Proper shipping name PHTHALIC ANHYDRIDE
Hazard Class 8
Packing group III
Special Provisions for Transport Not Classified as Hazardous for Transport

IATA

 

 

UN        Number                                          UN 2214
Proper shipping name PHTHALIC ANHYDRIDE
Hazard Class 8
Packing group III
Special Provisions for Transport Not available.

IMDG/IMO

 

 

UN        Number                                          UN 2214
Proper shipping name PHTHALIC ANHYDRIDE
Hazard Class 8
Packing group III
Special Provisions for Transport Not Classified as Hazardous for Transport

 

 

 

Fedral and State Regulation  Connecticut hazardous material survey.: Phthalic anhydride Illinois toxic substances disclosure to employee act: Phthalic anhydride Illinois chemical safety act: Phthalic anhydride New York release reporting list: Phthalic anhydride Rhode Island RTK hazardous substances: Phthalic anhydride Pennsylvania RTK: Phthalic anhydride Minnesota: Phthalic anhydride Michigan critical material: Phthalic anhydride Massachusetts RTK: Phthalic anhydride
Other Regulation OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada) CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid.
DSCL (EEC)                        R22- Harmful if swallowed. R26- Very toxic by inhalation. R38- Irritating to skin. R41- Risk of serious damage to eyes. S1/2- Keep locked up and out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28- After contact with skin, wash immediately with plenty of [***] S36/37- Wear suitable protective clothing and gloves. S39- Wear eye/face protection. S45- In case of accident or if you feel unwell,

 

 

HMIS                               
Health Hazard : 3
Fire Hazard : 1
Reactivity : 1
Personal Protection : E

 

 

 

Fire :                              
Health Hazard : 3
Fire Hazard : 1
Reactivity : 0
Specific Hazard

 

 

 

 

Other Information

 

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

 

 

 

 

Product Name Sodium Fluoride
Part Number RXSOL-19-8203-025

Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.

VASHI ,NEW BOMBAY 400703 INDIA

 

Phone +91 22 65113333 / 5555 / 9999
Fax +91 22 2781 1318 :::AOH :0091 9821214367
Email 123@rxmarine.com
Website www.rxmarine.com

 

Name     of        Substance                          Cas Number EC Number Wight %
Sodium Fluoride 7681-49-4 231-667-8  100%

 

 

Signal Word                       Danger
Hazard Statements H301 Toxic if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
EUH032 Contact with acids liberates very toxic gas.
Precautionary statements - prevention P280 Wear protective gloves.
Precautionary statements  response

P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water fo several minutes. Remove contact  lenses, if present and easy to do. Continue rinsing.
P308 + P310 IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.

  

 

Eye Contact

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Skin Contact In case of contact, immediately flushes skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Inhalation: Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur.
Ingestion: Do not induce vomiting. Obtain medical attention.If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration.
Notes to Physician Treat symptomatically

 

Flammability                                                  Not Flammable
Flash Point Not Applicable
Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Hazardous combustion products Not available
Protective Equipment Use personal protective equipment.
Specific Hazards Arising from the Chemical Not combustible. Ambient fire may liberate hazardous vapours. Fire may cause evolution of: Hydrogen fluoride
Special protective equipment for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

 

Spillage

Use appropriate tools to put the spilled solid in a convenient waste disposal container.Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed.

Personal Protection Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8.
Enviromental Precaution Do not let product enter drains.
Methods and materials for
containment and cleaning
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up the affected area. Avoid generation of dust

 

 

Handling

Do not ingest. Do not breathe dust. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, metals, acids, alkalis.

Storage Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorised persons.Protect from moisture. Store away from foodstuffs
Advice on general occupational hygiene Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.

 

Engineering Control Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Personal Protection Eye/face Protection: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin and body protection: Wear appropriate protective gloves and clothing to prevent skin exposure. Respiratory Protection :  Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator exposure limits are exceeded or if irritation or other symptoms are experienced.
Other Protection Measure Handle in accordance with good industrial hygiene and safety practice.
Exposure Limit TWA: 2.5 (mg/m3) from NIOSH Consult local authorities for acceptable exposure limits

                                                        gloves                suit                

                                                     Gloves                       Suit                          

 

Form         Crystal / Solid
Colour White
Odour Odourless
Odor Threshold Not Applicable
pH 10.2 at 40 g/l 20 °C 
Melting Point 996 °C  (decomposition)
Boiling Point 1,695 °C at 1,013 hPa
Flash Point Not Applicable
Evaporation Rate Not Applicable
Flammability (solid, gas) No Data Available
Explosive limits No Data Available
Vapour pressure 1 hPa at 1,077 °C
Vapour Density No information available.
Specific Gravity 2.8 g/cm3 at 20 °C
Partition coefficient No data available
Explosive properties None
Solubility Soluble in water 50 g/l at 20 °C
Ignition temperature No information available.
Oxidizing properties None

 

Reactivity                        Reacts with acids..
Stability The product is chemically stable under standard ambient conditions.
Possibility of hazardous reactions Generates dangerous gases or fumes in contact with: acids Possible formation of : Hydrogen Fluoride.
Conditions to avoid Strong Heating
Incompatible materials Reactive with oxidizing agents, metals, acids, alkalis.
Hazardous Polymerization Hazardous polymerization does not occur.

 

Rout Of Entry Inhalation. Ingestion.
Toxicity to Animal Acute oral toxicity (LD50): 52 mg/kg [Rat].
Toxic Effects on Human May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Special Remarks on other Toxi  Effects on Humans:                      

Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.

Further Information After absorption: We have no description of any toxic symptoms. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice.
Systemic effects:
Cardiac irregularities, respiratory arrest, Nausea, Unconsciousness, death The following applies to soluble inorganic fluorides in general: may cause irritations to burns in contact with eyes, skin, mucous membranes. Systemic effect: drop in blood calcium level, agitation, spasms, cardiovascular disorders, CNS disorders. Handle in accordance with good industrial hygiene and safety practice

 

 

Eco Toxicity Toxicity to fish : LC50 Gambusia affinis (Mosquito fish): 925 mg/l; 96 h (IUCLID). Toxicity to daphnia and other aquatic invertebrates EC50 Daphnia magna (Water flea): 338 mg/l; 48 h (IUCLID)
COD and BOD 5 Not Available
Products Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Mobility in soil No Information available
Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
Other adverse effects Hazard for drinking water supplies. Discharge into the environment must be avoided.

 

 

 

 

Waste treatment Method Waste material must be disposed of in accordance with the national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.

DOT

 

UN        Number                                          UN 1690
Proper shipping name

SODIUM FLUORIDE, SOLID

Hazard Class 6.1
Packing group III

TDG

 

UN        Number                                          UN 1690
Proper shipping name

SODIUM FLUORIDE, SOLID

Hazard Class 6.1
Packing group III

IATA

 

UN        Number                                          UN 1690
Proper shipping name

SODIUM FLUORIDE, SOLID

Hazard Class 6.1
Packing group III

IMDG/IMO

 

 

UN        Number                                          UN 1690
Proper shipping name

SODIUM FLUORIDE, SOLID

Hazard Class 6.1
Packing group III

 

Fedral and State Regulation California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. Connecticut hazardous material survey.: Sodium fluoride Illinois chemical safety act: Sodium fluoride New York release reporting list: Sodium fluoride Rhode Island RTK hazardous substances: Sodium fluoride Pennsylvania RTK: Sodium fluoride Massachusetts RTK: Sodium fluoride Massachusetts spill list: Sodium fluoride New Jersey: Sodium fluoride New Jersey spill list: Sodium fluoride Louisiana spill reporting: Sodium fluoride.
Other Regulation OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
WHMIS (Canada) CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC). CLASS D-2B: Material causing other toxic effects (TOXIC).
DSCL (EEC)                        R25- Toxic if swallowed. R32- Contact with acids liberates very toxic gas. R36/38- Irritating to eyes and skin. S22- Do not breathe dust. S36- Wear suitable protective clothing. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

 

 

HMIS                               
Health Hazard : 2
Fire Hazard : 0
Reactivity : 0
Personal Protection : E

 

 

Fire :                              
Health Hazard : 3
Fire Hazard : 0
Reactivity : 0
Specific Hazard

 

 

Other Information

 

The information above is believed to be accurate and represents the  best information   currently    available  to us.  However,   we   make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and  weassume  no liability resulting from its use. Users should make  their  own  investigations  to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International  has been advised of the possibility of such damages.

 
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